摘要
综述了近 4 0年来杂环化合物和一氧化碳在金属络合物催化下的羰基化反应 ,详细讨论了不同类型反应的有关机理 ,并展望了该领域的研究前景。
The research progress on carbonylation reactions of heterocycles (such as epoxides and aziridines) during the last 40 years is reviewed in the presence of transition metal complex catalysts. The reaction mechanisms of both carbonylative ring expansion and carbonylative polymerization are discussed in detail. The perspective on this research field is also suggested.
出处
《化学进展》
SCIE
CAS
CSCD
2004年第6期989-999,共11页
Progress in Chemistry
关键词
杂环
过渡金属络合物催化剂
羰基化
反应机理
heterocycles
transition metal complex catalysts
carbonylation
reaction mechanism
