4,4’-二氨基二苯基醚四缩水甘油胺的合成

Synthesis of tetraglycidyled 4,4' dianiline ether

本文以ＤＤＥ（４，４’二氨基二苯基醚４，４’Ｄｉａｍｉｎｏｄｉｐｈｅｎｙｌｅｔｈｅｒ）和环氧氯丙烷为原料，经两步反应合成新型多官能团环氧树脂ＴＧＤＡＥ（４，４’二氨基二苯基醚四缩水甘油胺Ｔｅｔｒａｇｌｙｃｉｄｙｌａｔｅｄ４，４’ｄｉａｎｉｌｉｎｅｅｔｈｅｒ）．此反应条件温和，收率较高。

This paper reports a facile method of synthesis of tetraglycidyled 4,4' dianiline ether (TGDAE). The TGDAE was synthesized from 4,4' diamino diphenyl ether (DDE) with chloropropylene oxide by the addition and epoxidation in the presence of sodium hydroxide.