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草酸对沉积地层中Fe、Cu、Pb、Zn元素的淋滤实验研究 被引量:5

EXPERIMENTAL RESEARCH ON FUNCTION OF OXALIC ACID IN LEACHING OF Fe, Cu, Pb, Zn IN SEDIMENTARY STRATA
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摘要 利用准流动热液反应装置,进行了草酸与沉积地层中的Fe、Cu、Pb、Zn元素活化淋滤的成矿模拟实验,结果表明,草酸对地层中的金属元素有较强的活化萃取能力,最大淋滤量对应温度在125-150℃之间,通过对比实验液相和固相中金属量的变化、配合物稳定常数及实验淋滤率顺序,并结合曲仁盆地成矿特征。 The metallogenic simulated experiments of the activation leaching of Fe, Cu,Pb, Zn in the sedimentary strata by oxalic acid have been studied using quasi-flowing hydrothermal reaction equipment. The results show that the oxalic acid has a strong ability to activate and to extract the metal elements in the strata and the best leaching temperature range is from 125℃ to 150℃. Based on the metal contents in liquid and solid phase, complex stability constant and the leaching sequence combined with metallogenic feature in Quren basin, it is suggested that the ore-forming elements exist mainly in organic complex. And the results show that the organism may play an important role in the formation of the superlarge lead-zinc deposit in Fankou, Guangdong Province.
机构地区 中山大学地质系
出处 《地球化学》 CAS CSCD 北大核心 1995年第C00期177-182,共6页 Geochimica
基金 国家自然科学基金
关键词 成矿模拟实验 草酸 沉积地层 淋滤实验 准流动热液反应装置 活化萃取能力 有机配合物 oxalic acid flowing simulated experiment activation leaching organic complex strata-bounded ore deposit
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