Silica-supported Poly-γ-aminopropylsilane Cu^(2+)-Pd^(2+) Complex: A New Catalyst System for Heck Vinylation Reaction

Silica-supported Poly-γ-aminopropylsilane Cu^(2+)-Pd^(2+) Complex: A New Catalyst System for Heck Vinylation Reaction

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摘要 In this paper, a new silica-supported poly-γ-aminopropylsilane Cu2+-Pd2+ complex was studied in Heck vinylation reaction of aryl iodide with olefins. The catalyst is highly active and stereoselective at 70-100℃, and can be resused after washing without loss in activity. In this paper, a new silica-supported poly-γ-aminopropylsilane Cu2+-Pd2+ complex was studied in Heck vinylation reaction of aryl iodide with olefins. The catalyst is highly active and stereoselective at 70-100℃, and can be resused after washing without loss in activity.

作者 RenXianZHOU ShaoFenZHAO

机构地区 InstituteofCatalysis CollegeofChemicalEngineering

出处《Chinese Chemical Letters》 SCIE CAS CSCD 2004年第7期856-858,共3页 中国化学快报（英文版）

关键词 CATALYST Heck reaction poly-γ-aminopropylsilane. Catalyst, Heck reaction, poly-γ-aminopropylsilane.

分类号 O634.41 [理学—高分子化学] O643.36 [理学—物理化学]

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Chinese Chemical Letters

2004年第7期

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Silica-supported Poly-γ-aminopropylsilane Cu^(2+)-Pd^(2+) Complex: A New Catalyst System for Heck Vinylation Reaction

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