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Biphasic Catalytic Hydroformylation of 1-Dodecene in Micellar System with Cationic Gemini Surfactants 被引量：1

Biphasic Catalytic Hydroformylation of 1-Dodecene in Micellar System with Cationic Gemini Surfactants
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摘要 The promotion effect of cationic gemini surfactants for the hydroformylation of 1-dodecene in the organic/aqueous biphasic catalytic system is reported. The hydroformylation reaction in the presence of gemini surfactant occurred with higher turnover frequency and higher selectivity for linear aldehyde than using conventional monomeric surfactant CTAB. The promotion effect of cationic gemini surfactants for the hydroformylation of 1-dodecene in the organic/aqueous biphasic catalytic system is reported. The hydroformylation reaction in the presence of gemini surfactant occurred with higher turnover frequency and higher selectivity for linear aldehyde than using conventional monomeric surfactant CTAB.
作者 MinLI BinXU HuaCHEN HongJieZHENG XueYuanHUANG YaoZhongLI XianJunLI
机构地区 DepartmentofChemistry
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2004年第9期1022-1024,共3页 中国化学快报（英文版）
关键词 1-十二烯 胶体系统 阳离子型 两性离子型表面活性剂 两相催化反应 羰基化作用 铑催化剂 Hydroformylation, gemini surfactant, 1-dodecene, rhodium catalyst.
分类号 O623.12 [理学—有机化学]
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参考文献7

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  • 2M. Li,Y. Z. Li,H. Chen,Y. E. He,and X. J. Li.Studies on 1-dodecene hydroformylation in biphasic catalytic system containing mixed micelle[].J Mol Catal A-Chem.2003
  • 3Zana R,Benrraou M,Rueff R.Alkanediyl-α, ω-bis (dimethylalkylammonium bromide) surfactants. 1. effect of the spacer chain length on the critical micelle concentration and micelle ionization degree[].Langmuir.1991
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同被引文献21

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Chinese Chemical Letters
2004年 第9期

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