磷酸酯桥联配合物{Fe_4Ni(NSI)_4[O_2P(OPh)_2]_4(μ-OH)_2}·CH_3OH的合成、表征和晶体结构

Synthesis and Characterization of bridge ligard of phosphate complex {Fe_4Ni(NSI)_4[O_2P(OPh)_2]_4(μ-OH)_2}·CH_3OH and its Crystal Structure

合成了磷酸酸酯桥联配合物 {Fe4Ni(NSI) 4 [O2 P(OPh) 2 ]4(μ -OH) 2 }·CH3 OH ,并得到其晶体结构 ,在 5～ 30

The complex {Fe 4Ni(NSI) 4[O 2P(OPh) 2] 4(μ-OH) 2}·CH 3OH was synthesized and characterized with IR spectroscopy and X-ray diffraction method.The crystal belonged Monoclinic with space group of P2(1)/n.The cell parameters were a=17.636(8)?,b=30.619(13)?,c=18.436(8)?,β=105.842(8)°,V=9 578(7)? 3,Z=4,D=1.376 Mg/m 3,μ=0.924 mm -1,F(000)=4088.The final R1=0.1912,wR2=0.3285.The magnetic susceptibility of the complex had been measured in the range 5～300 K.