Synthesis and Photochemical Properties of a New Substituted Phenol Covalently Linked to Ruthenium (Ⅱ) Tris-bipyridine Containing Four Ester Groups as Sensitizer
Synthesis and Photochemical Properties of a New Substituted Phenol Covalently Linked to Ruthenium (Ⅱ) Tris-bipyridine Containing Four Ester Groups as Sensitizer
摘要
As photosensitizer for solar cell, a new ruthenium (Ⅱ) complex with four ester groups hadbeen synthesized, in which a phenol substituted by {[(2-hydroxy-5-tert-butylbenzyl)(pyridyl-2-methyl)amino]methyl} is covalently linked to ruthenium (Ⅱ) tris-bipyridine. The structures ofthe new compounds were confirmed by NMR and ESI-MS spectra. The electrochemical andphotochemical properties were also studied.
As photosensitizer for solar cell, a new ruthenium (Ⅱ) complex with four ester groups hadbeen synthesized, in which a phenol substituted by {[(2-hydroxy-5-tert-butylbenzyl)(pyridyl-2-methyl)amino]methyl} is covalently linked to ruthenium (Ⅱ) tris-bipyridine. The structures ofthe new compounds were confirmed by NMR and ESI-MS spectra. The electrochemical andphotochemical properties were also studied.
参考文献12
-
1[1](a) B. O'Regan, M. Gratzel, Nature, 1991, 353, 737.(b) M. K. Nazeeruddin, A. Kay, J. Rodicio, et al., J. Am. Chem. Soc., 1993, 115, 6382.
-
2[2]J. Desilverstro, M. Gratzel, L. Kavan, et al., J. Am. Chem. Soc., 1985, 107, 2988.
-
3[3]A. Tran, H. Wolpher, L. Sun, et al., manuscript in preparation.
-
4[4]R. Argazzi, C. A. Bignozzi, Inorg. Chem., 1994, 33, 5741.
-
5[5]L. Sun, M. Burkitt, M.Tam, et al., J. Am. Chem. Soc., 1999, 121, 6834.
-
6[6]Y. Ogata, A. Kawasaki, F. Sugiura, Tetrohedron, 1968, 24, 5001.
-
7[7]L.F. Lindoy, G. V. Meehan, N. Svenstrup, Synthesis, 1998, 7, 1029.
-
8[8]S. Kim, C. H. Oh, J. S. Ko, etal.,J. Org. Chem., 1985,50, 1927.
-
9[9]K.F. Lane, Synthesis, 1975, 3, 135.
-
10[10]R. Aldred, R. L. Johnston, J. Neilan, et al., J. Chem. Soc., Perkin Trans. 1, 1994, 1823.
-
1SONG Jianlan (staff reporter).Rosier future for solar energy conversion[J].Bulletin of the Chinese Academy of Sciences,2008,22(4):219-220.
-
2李勇.江菱HY-5远红外电磁炉故障一则[J].家电检修技术,2012(11):47-47.
-
3秦元东,王晶晶,邹英华,杨蓉,王维波,侯原军,肖绪瑞,张宝文,曹怡.TiO_2的联吡啶-钌化合物敏化及电子转移过程[J].物理化学学报,1998,14(6):520-526. 被引量：4
-
4科技信息[J].精细化工原料及中间体,2009(5):51-51.
-
5郑大琼.CY-5、CY-A型液压操作机构故障处理及改进[J].云南电力技术,2007,35(4):39-40.
-
6ShiGuoSUN XiaoJunPENG YongQianXU LeiSHI YunLingGAO LiChengSUN.Studies of a Series of Novel Rhenium（Ⅰ） Bipyridyl Dyes for Solar Cells[J].Chinese Chemical Letters,2005,16(5):677-680.
-
7赵清锐（编译）.阳光采集和空穴传输的高消光钌化合物[J].科学新闻,2008(23):5-5.
-
8遇鑫遥,蒋仲庆,孟月东.Preparation of Anodes for DMFC by Co-Sputtering of Platinum and Ruthenium[J].Plasma Science and Technology,2010,12(2):224-229.
-
9姜璐璐,蒋玉荣,张丛丛,陈泽章,秦瑞平,马恒.Fullerene solar cells with cholesteric liquid crystal doping[J].Chinese Physics B,2016,25(9):153-156.
-
10方自力.SZY—5／IBMPC厂站端当地综合自动化系统简介[J].电力自动化设备,1993,13(3):45-47.
