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Room Temperature Ionic Liquid: a Powerful Additive of Mn(Salen) Catalyzed Oxidation of sec-Alcohols

Room Temperature Ionic Liquid: a Powerful Additive of Mn(Salen) Catalyzed Oxidation of sec-Alcohols
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摘要 A simple, mild, efficient Mn(salen)-catalyzed oxidation system of secondaty alcohols,in which the ionic liquid [bmim]PF_6 acts as a powerful additive, has been described. The reactionproceeded with higher efficiency. The catalyst was more easier to recycle in ionic liquid[bmim]PF_6 with a well-proportioned CH_2C1_2 than in the single CH_2Cl_2 or ionic liquid. A simple, mild, efficient Mn(salen)-catalyzed oxidation system of secondaty alcohols,in which the ionic liquid [bmim]PF_6 acts as a powerful additive, has been described. The reactionproceeded with higher efficiency. The catalyst was more easier to recycle in ionic liquid[bmim]PF_6 with a well-proportioned CH_2C1_2 than in the single CH_2Cl_2 or ionic liquid.
作者 Jing Wei LI Wei SUN Li Wen XU Chun Gu XIA Hong Wang WANG State Key Laboratory for Oxo Synthesis & Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sicences, Lanzhou 730000
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2004年第12期1437-1440,共4页 中国化学快报（英文版）
关键词 Salen Mn ionic liquid sec-alcohols oxidation. Salen Mn ionic liquid, sec-alcohols oxidation.
分类号 O643.3 [理学—物理化学]
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Chinese Chemical Letters
2004年 第12期

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