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过氧亚硝酸盐的化学特性与化学发光反应 被引量：3

Chemical Characters and Chemiluminescent Reaction of Peroxynitrite
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摘要 过氧亚硝酸盐 (ONOO )是一氧化氮衍生物 ,由一氧化氮和超氧阴离子反应生成 ,它是很强的生物氧化剂 ,具有高的反应活性和不稳定性。本文评述了过氧亚硝酸盐的形成、生物地位、分解、测定 ,重点介绍过氧亚硝酸盐化学发光研究以及与二氧化碳的反应 ,并对其发展前景进行展望。引用参考文献 15 2篇。 Peroxynitrite is a derivative of nitric oxide and formed by the rapid diffusion controlled reaction between nitric oxide and superoxide. It is highly reactive and unstable oxidant. In this review, the main discussions include the formation, biological consequences, decomposition and measurement of peroxynitrite. Moreover, the peroxynitrite chemiluminescence and its reaction with CO 2 are focused. The future prospects are described in brief. 152 references are cited in this paper.
作者 吕超 魏彦林 林金明
机构地区 中国科学院生态环境研究中心
出处 《世界科技研究与发展》 CSCD 2004年第4期34-47,共14页 World Sci-Tech R&D
基金 国家杰出青年科学基金项目 (No .2 0 12 5 5 14)
关键词 过氧亚硝酸盐 一氧化氮 化学发光反应 超氧阴离子 化学发光 衍生物 不稳定性 反应活性 分解 二氧化碳 peroxynitrite, chemiluminescence, review
分类号 O611 [理学—无机化学]
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参考文献152

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  • 2Houk K.N., Condroski K.R., Pryor W.A. Radical and concerted mechanisms in oxidations of amines, sulfides and alkenes by peroxynitrite, peroxynitrous acid and the peroxynitrite-CO2adduct: density functional theory transition structures and energetics. J. A
  • 3Yermilov V., Yoshie Y., Rubio J. , Ohshima H. Effects of earbon dioxide/bicarbonate on induction of DNA single-strand breaks and formation of 8-nitroguanine, 8-oxoguanine and base-propenal mediated by peroxynitrite. FEBS Lett. , 1996, 399:67～70
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世界科技研究与发展
2004年 第4期

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