混合配体、稀土三元配合物的研究——Ⅳ.氯化铜(Ⅱ)、8-羟基喹啉、对羟基苯甲酸三元配合物的合成、表征及电学性质

Studies on Synthesis and Characterization of Ternary Complex of Cu(Ⅱ)with 8-quinolinol and p-Hydroxybenzoic Acid

本文报道了新的三元配合物[Cu(H_2O)8-O_x)(p)·(1/2)H_2O](HP=p-HO-C_6H_4COOH)的合成方法.应用元素分析、溶解性试验、摩尔电导、红外光谱、X 射线粉末衍射、差热—热重分析及配合物的导电性质等手段,对三元配合物进行了结构与性质的研究.

In this paper the synthesis and solubility of Cu(H_2O)(8-O_x)(p-HO-C_6H_4COOH)1/H_2O were reported.Its composition,molar conductance,thermo-gravimetric differential thermal analysis,X-ray powder diffraction and infrared spectrawere studied.The complex obeys activition type electric conduction pattern,so it is agood semiconducting material.