摘要
The precipitating regulation and mechanism of TCP phase (μ phase and σ phase) are studied, using electron hole number (EHN) theory, phase analysis technology and TEM observation. The results indicate that the EHN in studied alloy is 2.311-2.348 which is higher than that of critical EHN of μ phase precipitate (2.30), so μ phase could precipitate if there is enough thermo-exposition. In contrast, the calculated EHN is less than that of critical EHN of σ phase precipitate (2.52). However the σ phase is also observed by TEM. Enrich of Cr and Mo around γ phase after γ′phase precipitated leads to σ phase precipitated.
The precipitating regulation and mechanism of TCP phase (μ phase and σ phase) are studied, using electron hole number (EHN) theory, phase analysis technology and TEM observation. The results indicate that the EHN in studied alloy is 2.311-2.348 which is higher than that of critical EHN of μ phase precipitate (2.30), so μ phase could precipitate if there is enough thermo-exposition. In contrast, the calculated EHN is less than that of critical EHN of σ phase precipitate (2.52). However the σ phase is also observed by TEM. Enrich of Cr and Mo around γ phase after γ′phase precipitated leads to σ phase precipitated.