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Catalytic Performance of CeO_2/ZnO Nanocatalysts on the Oxidative Coupling of Methane with Carbon Dioxide and their Fractal Features 被引量:1

Catalytic Performance of CeO_2/ZnO Nanocatalysts on the Oxidative Coupling of Methane with Carbon Dioxide and their Fractal Features
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摘要 CeO2/ZnO nanocatalysts were prepared from the coupling route of homogeneous precipita-tion with microemulsion and the impregnation method. The catalytic performance of these two kinds of catalysts on the oxidative coupling of methane with carbon dioxide was tested and compared; the frac-tal behavior of the nanocatalysts was analyzed using fractal theory. The CeO2/ZnO nanocatalysts had much higher activity than the catalysts prepared by impregnation method. There was no regular relation-ship between the average size of CeO2/ZnO nanocatalysts and their catalytic performance; however, the conversion of methane increased with the increase of the fractal dimension of CeO2/ZnO nanocatalysts. CeO2/ZnO nanocatalysts were prepared from the coupling route of homogeneous precipita-tion with microemulsion and the impregnation method. The catalytic performance of these two kinds of catalysts on the oxidative coupling of methane with carbon dioxide was tested and compared; the frac-tal behavior of the nanocatalysts was analyzed using fractal theory. The CeO2/ZnO nanocatalysts had much higher activity than the catalysts prepared by impregnation method. There was no regular relation-ship between the average size of CeO2/ZnO nanocatalysts and their catalytic performance; however, the conversion of methane increased with the increase of the fractal dimension of CeO2/ZnO nanocatalysts.
出处 《Journal of Natural Gas Chemistry》 CAS CSCD 2004年第3期167-171,共5页 天然气化学杂志(英文版)
关键词 METHANE carbon dioxide oxidative coupling CeO2/ZnO nanocatalysts fractal dimension methane, carbon dioxide, oxidative coupling, CeO2/ZnO nanocatalysts, fractal dimension
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  • 1Changlin Chen,Yide Xu,Guangjin Li,Xiexian Guo. Oxidative coupling of methane by carbon dioxide: a highly C2 selective La2O3/ZnO catalyst[J] 1996,Catalysis Letters(3-4):149~153

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