芳酰基-双二茂铁烷的合成及还原反应

Synthesis and Reductions of Aroyl-Bisferrocenylalkanes

由双二茂铁乙烷、双二茂铁丁烷和双二茂铁戊烷的芳酰化反应,合成了十二种芳酰基双二茂铁烷,将它们进行还原得到四种苄羟基双二茂铁烷,对所有这些新化合物进行了元素分析,红外和核磁氢谱测定,确证了它们的组成和结构。

Twelve Aroyl-BisFerrocenylAlkanes were synthesized by the aroylation reactions of BisFer- rocenylethane、bisferrocenylbutane、BisFerrocenylpentane with Aroylchloride in the presence of Aluminum chloride. Reduction reactions of Aroyl-BisFerrocenylakanes were carried out and gives four benzylhydoyl-BisFerrocenylalkanes. The constituent and structure of all these new com- pounds were confirmed by elemental analysis、IR and H^1NMR spectra