摘要
采用射频磁控溅射在扩镓硅基上溅射Ga2O3 氮化反应生长GaN薄膜。用X射线衍射 (XRD)、扫描电镜(SEM)、选区电子衍射 (SAED)、光电能谱 (XPS)和荧光光谱 (PL)对样品进行结构、形貌、组分和发光特性的分析。XRD、SAED和XPS分析证明 ,采用此方法得到六方纤锌矿结构的GaN多晶膜。SEM显示薄膜由均匀、结合紧密的纳米微晶粒组成 ,其直径约为50~100nm。PL发光谱显示位于344nm处 ,相对于365nm明显蓝移的带边峰 。
GaN films were grown through nitriding the Ga 2 O 3 films formed on the Ga-diffused Si(111)subˉstrate by r.f.magnetron sputtering.X-ray diffraction(XRD),scanning electron microscopy(SEM),selected area electron diffraction(SAED),X-ray photoelectron spectroscopy(XPS)and photoluminescence(PL)were employed to analyze the structure,surface morphology and component and optical emission properties of the prepared samples.The XRD,SAED and XPS patterns indicated that the growing films were of hexagonal polyˉcrystalline GaN films and the SEMimage showed that the films were composed of uniform GaN nanoparticals with diameters of50~100nm.The PLpeak was at344nmwhich was blue shifted fromthat of the bulk GaN by21nm.This phenomenon might be attributed to the recombination of free-carrier.
出处
《分析测试学报》
CAS
CSCD
北大核心
2004年第6期65-68,共4页
Journal of Instrumental Analysis