期刊文献+

氢醌化合物对针叶木硫酸盐纸浆氧脱木素的影响 被引量:5

Effect of Hydroquinone Compounds on Oxygen Delignification of Softwood Kraft Pulp
下载PDF
导出
摘要 研究了具有氧化还原性的氢醌类化合物作为氧脱木素过程的添加物。结果表明 ,氢醌的加入可以降低纸浆的卡伯值 ,提高氧脱木素的选择性。其原因是氢醌的存在可以提高O2 转化成为含氧的活性反应产物 ,加速木素中甲氧基的脱除 ,有利于破坏木素的结构和脱除木素。 The reductive compounds, especially compounds with hydroquinone structure,take an important role in alkaline oxygen delignification system to improve the selectivity of lignin removal. The reason is that these compounds are benefit to increase the oxygen active species in the oxygen delignification system, which can accelerate demethoxylation and to destroy lignin. The compounds in liquor after oxygen delignification were analyzed by Py-GC_MS to show that hydroquinone compounds can improve lignin removal and protect cellulose while hemicellulose is removed with lignin.
出处 《中国造纸学报》 CAS CSCD 北大核心 2004年第2期32-36,共5页 Transactions of China Pulp and Paper
关键词 氧脱木素 纸浆 针叶木 卡伯值 醌类 脱除 氢醌 含氧 类化合物 硫酸盐 hydroquinone compounds kraft pulp oxygen delignification methanol
  • 相关文献

参考文献10

  • 1Gierer J,Reibjom T,Yang E, et al. Formation and involvement of radicals in oxygenn delignification studied by the autoxidation of lignin and carbohydrate model compounds[ J ]. J. Wood Chemistry and Technology,2001, 21(4): 313
  • 2Yokoyama T, Matsumoto Y,Meshitsuka G. Reaction selectivity during alkaline oxygen delignification of pulp[ C]. 2nd ISETPP, Emerging technologies of pulping and papermaking, South China University of Technology Press, 2002, Guangzhou, China, 11
  • 3Reid D W, Ayton J, Mullen T. CPPA oxygen delignification survey[ J ].Pulp and Paper Canada, 1998, 99(11): 43
  • 4Chen S - L, Lucia L A. Fundamental Insight into the Mechanism of Oxygen Delignification of Kraft Pulps: Influence of a Novel Carbohydrate Protective System[J]. Cell. Chem. Technol, 2002, 36:339
  • 5Fu S, Lucia L A. Investigation of the Chemical Basis for Inefficient Removal of Lignin Removal in Softwood Kraft Pulp during Oxygen Delignification[J]. Ind. Eng. Chem. Res, 2003, 42, 4269
  • 6Tench L, Harper S. Oxygen bleaching practices and benefits: an overview[J]. Tappi, 1987, 70(11): 55
  • 7McDonough T. Oxygen delignification, in Pulp Bleaching: Principles and Practice[C]. Dence C W and Reeve D W, Eds. Tappi Press, Atlanta,1996, 215
  • 8Smith L, Calvert D W, Robert A, et al. Delignification and bleaching of cellulose pulp, South Africa Pat no 68/3771,1968-06-13
  • 9SolinasMandProustA, Oxygen bleaching process for cellulose pulps with a polyhydric alcohol cellulose protector. US Pat no 5609723.1997-03-11
  • 10Zhu JY, Liu PH, Xin-Sheng Chai,Bullock K RTejaA. Henry's Law Constant of Methanol in Pulping Spent Liquor[ J ]. Environ Sci. & Techno,2000,34(9): 1742

同被引文献101

引证文献5

二级引证文献12

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部