某些烃基三氯化锡配合物的合成及性质

SYNTHESIS AND DETERMINATION OF THE PROPERTIES OF THE COMPLEXES OF SOME HYDROCARBYLTIN TRICHLORIDES

合成了7个烃基三氯化锡的配合物RSnCl_3·nL(R=Bu,EtOCOCH_2CH_2,BuOCOCH_2CH_2;n=1,2;L=P_3~hP,P_3~hPO,DMSO,HMPA),其中有4个配合物未见文献报道。通过元素分析、IR、NMR等对上述配合物进行了表征,并对其性质作了初步研究。

Seven complexes of the type rSnCl_3nL (R=Bu,EtOCOCH_2CH_2,BuOCOCH_2CH_2; n=1,2; L=P_3~h P, P_3~hPO, DMSO, HMPA) are synthesized, in which four compounds are not reported in literature, and characterized by means of elemental analysis, IR, and NMR spetroscopy. Their properties are discussed elementarily.