Anodic Synthesis and Characterization of Na-Pb-O, Na-Pb-Bi-O Crystals

Anodic Synthesis and Characterization of Na-Pb-O, Na-Pb-Bi-O Crystals

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摘要 Crystals of Na-Pb-O and Na-Pb-Bi-O were electrosynthesized on the anode from molten salts. The resulting crystals have a hexagonal structure, in which the base ions (Pb and Bi) are in high oxidation states. By using KOH/NaOH (atomic ratio K:Na=1:1) mixture as a flux, incorporation of K ions into the lattice is inhibited while incorporation of Bi ions is enhanced. The magnetic measurement shows that the Na-Pb-Bi-O crystals are dominated by diamagnetism. Crystals of Na-Pb-O and Na-Pb-Bi-O were electrosynthesized on the anode from molten salts. The resulting crystals have a hexagonal structure, in which the base ions (Pb and Bi) are in high oxidation states. By using KOH/NaOH (atomic ratio K:Na=1:1) mixture as a flux, incorporation of K ions into the lattice is inhibited while incorporation of Bi ions is enhanced. The magnetic measurement shows that the Na-Pb-Bi-O crystals are dominated by diamagnetism.

作者 LiMeiQIU FenLIU LiangZhongZHAO

机构地区 InstituteofChemistry

出处《Chinese Chemical Letters》 SCIE CAS CSCD 2005年第1期78-80,共3页 中国化学快报（英文版）

关键词 Lead complex oxides anodic electrosynthesis crystal growth chacacterization. Lead complex oxides, anodic electrosynthesis, crystal growth, chacacterization.

分类号 O741.5 [理学—晶体学] O78 [理学—晶体学]

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1M L Norton, Mat Res Bull, 1989, 24, 1391.
2R G Lava, T Siegrist, WF Peck, et al, Phys Rev B, 1991, 44, 9746.
3S Kodialam, V C Korthius, R DI Hoffmann, et al, Mat Res Bull, 1992, 27, 1379.
4T N Nguyen, D M Giaquinta, W M Davis, et al, Chem Mater, 1993, 5, 1273.
5H Y Tang, C S Lee, M K Wu, Physica C, 1994, 231,325.
6H Y Tang, H Y Hshu, C S Lee, et al, J Electrochem Soc, 1997, 144, 16.
7L Z Zhao, C Dong, J B Zhang, et al, Solid State Commun, 1998, 106, 227.
8L Zhanlz, L Z Zhao, C Donlz, el al, solid State Commun 2000, 113 349.
9P E Werner, L Eriksson, MWestdahl, J Appl Crystallogr, 1985, 18, 367.
10C D Wagner, W M Riggs, L E Davis, et al, Handbook of X-ray Photoelectron Spectroscopyl MinnesotaUSA, 1979, p 160.

1李伟善,江琳才.利用成对电解法合成电催化二氧化锰和金属锰[J].华南师范大学学报（自然科学版）,1990,22(1):52-56.
2褚道葆,张莉艳,张金花,张秀梅,尹晓娟.NanoTiO_2-CNT复合膜电极在DMF溶液中对糠醛的异相电催化还原[J].物理化学学报,2006,22(3):373-377. 被引量：15
3M. P. Tosi(International Centre for Theoretical Physics, Strada Costiera 11, I-34014 Trieste, Italy).Nonmetal-Metal Transition in Solutions of Metals in Molten Salts[J].Journal of Materials Science & Technology,1998,14(1):1-8.
4Xindong Wang, Guangming Liu, Yanfang Liu, Shuzhen Duan Department of Physical Chemistry, University of Science and Technology Beliing, Beliing 100083. China).Cerium Oxide Film Prepared from Molten Salts[J].Rare Metals,2001,20(2):95-100. 被引量：1
5张婷,吴孟强,张树人,熊杰,王金明,张大海,何凤梅,李仲平.Permittivity and its temperature dependence in hexagonal structure BN dominated by the local electric field[J].Chinese Physics B,2012,21(7):505-512.
6Yu Cai CAO,Xuan Zhen JIANG.Novel Catalytic Hydrodechlorination of CCl_2F_2 over Supported PdCl_2-(n-C_4H_9)_4N^+Cl^- Molten salts[J].Chinese Chemical Letters,2001,12(6):533-536.
7GuangXiangLIU XiaoMingREN HengXU ChuanYiTANG GenHuaWU YouCunCHEN.Crystal Structures and Magnetic Properties of Two New Schiff Base Complexes[J].Chinese Chemical Letters,2004,15(9):1105-1108.
8Liliia Molotovska,Dmytro Shakhnin,Oleksandr Podyman,Viktor Malyshev,Nataliya Uskova,Viliam Pavlik.Electrochemical Synthesis of Chromium Silicides from Molten Salts[J].Journal of Chemistry and Chemical Engineering,2014,8(9):845-848.
9Hui Wang,Bi-Li Wang,Shu-Yun Ma.Synthesis of visible-light-driven TiO_(2) yolk-shell spheres with {001} facets dominated mesoporous shells[J].Chinese Chemical Letters,2013,24(3):260-263. 被引量：5
10郑朝贵,陈燕平,张立平.Investigation on Phase Diagram of Ternary System LaCl_3-BaCl_(2-)LiCl[J].Chinese Science Bulletin,1994,39(6):480-483.

Chinese Chemical Letters

2005年第1期

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Anodic Synthesis and Characterization of Na-Pb-O, Na-Pb-Bi-O Crystals

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