摘要
在H2SO4介质中,微量铱的存在对KIO4 偶氮胂DBM的褪色反应有明显的催化作用,探讨了该褪色反应的最佳条件及微量铱的测定方法,检出限为0.1μg/mL,铱含量在0.1~1.0μg/mL范围内符合比尔定律.
A spectrophotometric methed for the determination of Ir(Ⅲ) on the oxidative fading arsenazo- DBM with KIO_(4) in acid medium . the methed offers the advantages of simplicity,rapidity,and sensitivity. Beer's Law is obeyed from 0.1 to 1.0 μg Ir/ml and the determination limits is 0.1 μg Ir/ml. The catalytic Reaction occurs in water phase.
出处
《分析测试技术与仪器》
CAS
2004年第4期241-243,共3页
Analysis and Testing Technology and Instruments
关键词
铱
偶氮胂DBM
高碘酸钾
催化分光光度分析
Iridium
arsenazo-DBM
potassium periodate ruthenium
catalytic spectrophotometry