摘要
有机膦桥键羰基钴簇化物是烯烃低压羰化构醛的良好催化剂.对其催化机理及合成方法进行了探讨和研究,得到少量成品.开发了以钴粉和碘为原料直接制备无水碘化钴(CoI_2)的方法.
The title compound is a good catalyst for the hydroformylation of olefine to prepare normal aldehyde under low pressure.The catalytic mechanism of the cluster compound was discussed and the synthesis was studied.A new procedure for preparation of unhy- drous cobaltous iodide from cobalt powder and iodine was reported.
出处
《沈阳化工学院学报》
1993年第2期93-100,共8页
Journal of Shenyang Institute of Chemical Technolgy
关键词
催化
四核羰基钴簇
无水碘化钴
hydroformylation
catalysis
tetracobalt carbonyl cluster
unhydrous cobaltous iodide
