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Activity model and its application in CaO-FeO-SiO_2-MoO_3 quarternary system 被引量:9

Activity model and its application in CaO-FeO-SiO_2-MoO_3 quarternary system
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摘要 The activity model of CaO-FeO-SiO_2-MoO_3 quarternary system was establishedaccording to the coexistence theory of slag structure and the reduction thermodynamics of molybdenumoxide was discussed by applying this model. The activities of SiO_2 and MoO_3 decrease, while thatof CaO increases with increasing the basicity of slag. Among SiC, [C] and [Si] reactants, thereducing capability of SiC is the strongest, while that of [C] is the poorest at a high temperature(about 1873 K). It is advantageous to increase the yield of molybdenum by increasing the content of[Si] or [C]. Controlling of basicity of slag can prevent the oxidation loss of molybdenum. The activity model of CaO-FeO-SiO_2-MoO_3 quarternary system was establishedaccording to the coexistence theory of slag structure and the reduction thermodynamics of molybdenumoxide was discussed by applying this model. The activities of SiO_2 and MoO_3 decrease, while thatof CaO increases with increasing the basicity of slag. Among SiC, [C] and [Si] reactants, thereducing capability of SiC is the strongest, while that of [C] is the poorest at a high temperature(about 1873 K). It is advantageous to increase the yield of molybdenum by increasing the content of[Si] or [C]. Controlling of basicity of slag can prevent the oxidation loss of molybdenum.
出处 《Journal of University of Science and Technology Beijing》 CSCD 2004年第5期406-410,共5页 北京科技大学学报(英文版)
关键词 activity model molybdenum oxide THERMODYNAMICS direct reduction activity model molybdenum oxide thermodynamics direct reduction
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