期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

甘氨酸Schiff碱多核配合物的合成与表征 被引量：4

Synthesis and Characterization of Polynuclear Complexes with Glycine Schiff Base as Ligand
下载PDF
导出
摘要 合成了3 羧基水杨醛缩甘氨酸Schiff碱的双核铜、三核铜和异三核铜锌配合物.用元素分析,红外光谱、紫外可见光谱对配合物的组成和结构进行了表征.磁性测定表明,三核铜配合物的铜离子之间存在着较强的反铁磁性自旋交换相互作用,而在双核铜和异三核铜锌配合物中,由于距离较远,两个铜离子之间基本上没有磁性相互作用. 3-Carboxylsalicylidene glycine(H_(3)GS) and its complexes Na_(2)Cu_(2)(GS)_(2) ·2H_(2)O,Cu_(3)(GS)_(2) ·5H_(2)O,ZnCu_(2)(GS)_(2) ·5H_(2)O were synthesized and characterized with elemental analysis,IR and UV-vis spectroscopy.Magnetic measurement shows that there exists a strong antiferromagnetic spin exchange interaction in Cu_(3)(GS)_(2) ·5H_(2)O,while there is none spin exchange interaction in Na_(2)Cu_(2)(GS)_(2) ·2H_(2)O and ZnCu_(2)(GS)_(2) ·5H_(2)O due to the long distance between the Cu^(2+) ions.
作者 于兆文 姚莉 张武
机构地区 河南大学化学化工学院
出处 《河南大学学报（自然科学版）》 CAS 2004年第4期27-29,共3页 Journal of Henan University:Natural Science
基金 河南省自然科学基金资助项目(0111030700)
关键词 3-羧基水杨醛 甘氨酸 Sehiff碱 配合物 3-carboxylsalicylaldehyde glycine Schiff base complex
分类号 O641.4 [理学—物理化学]
  • 相关文献

参考文献5

二级参考文献14

  • 1陈新斌,郭灿城,梁本熹,饶宗海,杨治国.金属卟啉的合成及其对细胞色素P-450的模拟(ⅪⅤ)——钴卟啉对环己烷的单充氧催化作用[J].高等学校化学学报,1995,16(7):1051-1054. 被引量：15
  • 2KOLB H C, VANNIEUWENHZE M S, SHARPLESS K B. Catalytic Asymmetric Dihydroxylation[J]. Chem Rev, 1994, 94(8) :2483 - 2547.
  • 3TOKUNAGA M, LARROW J F, JACOBSEN E N. Asymmetic Catalysis with Water: Efficient Kinetic Resolution of Terminal Epoxides by Means of Catalytic Hydrolysis[J]. Science, 1997, 277(15) :936.
  • 4BRANDES B D, JACOBSEN E N. Synthesis of enantiopure 3-chlorostyrene oxide via an asymmetric epoxidation-hydrolytic kinetic resolution sequence[J]. Tetrahedron: Asymmetry, 1997, 8(23) : 3927 - 3933.
  • 5SCHAUS S E, BRANALT J, JACOBSEN E N. Total Synthesis of Muconin by Efficient Assembly of Chiral Building Blocks[j]. J Org Chem, 1998, 63(15) : 4876- 4877.
  • 6YU Q, WU Y K, WU Y L. Synthesis of a key intermediate for corossolin using hydrolytic kinetic resolution of epoxides[J].Chem Commun, 1999, (2):129- 130.
  • 7WILLIAMS O F, BAILAR JR J C. The Stereochemistry of Complex Inorganic Compounds XXIV Cobalt Stilbenediamine Complexes[J]. J Am Chem Soc, 1959, 81(17) :4464- 4469.
  • 8PIKUL S C, COREY E J. (1R, 2R )-( + )- AND (1S, 2S)-( + ) -1, 2-DIPHENYL-1, 2-ETHYLENEDIAMINE[J]. Org Syn, 1993, 71(1) :22 - 29.
  • 9陈新斌,桂明德,朱申杰,杨艳,郭灿城.新型Schiff碱单核及异双核配合物的合成及光谱特征[J].高等学校化学学报,1999,20(8):1238-1241. 被引量：15
  • 10陈新斌,杨艳,朱申杰,桂明德.Schiff碱配合物拟酶催化反应的取代基效应研究[J].高等学校化学学报,2000,21(11):1684-1687. 被引量：20

共引文献38

同被引文献35

  • 1归国风,柴雅琴,袁若,孙爱丽,王福昌.新型双核铜金属配合物为中性载体的硫氰酸根离子高选择性电极的研究[J].化学学报,2006,64(21):2185-2189. 被引量：10
  • 2Kahn O,Galy J,Journaux Y,et al.Synthesis,crystal structure and molecular conformations.and magnetic properties of a Cu(Ⅱ)-VO(Ⅱ) heterobinuclear complex:interaction between orthogonal magnetic orbitals[J].J Am Chem Soc,1982,104:2165-2176.
  • 3Journaux Y,Kahn O,Galy J,et al.Symmetry of the magnetic orbitals and extrange interaction in copper iron (CuⅡFeⅢ)and copper chromium (CuⅡCrⅢ)heterobinuclear complexes.Crystal structure of CuFe[(fsa)2en]Cl(H2O)(CH3OH)·CH3OH[J].J Am Chem Soc,1983,105:7585-7591.
  • 4Hodnett,M E,Mooney,P D.Antitumor activities of some schiff bases[J].J.Med Chem,1970,13(4):786-786.
  • 5Patrick D,Prasad P,Bibudhendra.The crystal structure of a novel copper(Ⅱ) complex with asymmetric lignd derived from L-histidine[J].Inorg.Chem,2003.42.7366-7368.
  • 6Metzler.D.M,Ikawa.M,Snell.E.E.A gengeral mchanism for witamin B62 catalyzed reactions[J].J.Am.Chem.Soc,1954,76(3):648-652.
  • 7Casela.L,Gullotti.M.Synthesis,stereochemistry and oxygenation of cobalt (Ⅱ)-pyridoxal model complexes.A new family of chiral dioxygen carriers[J].Inorg.Chem,1986,25,(9):1293-1295.
  • 8Kahn.O,Galy.J,Journaux.Y,et al.Synthesis.crystal structrue and molecular conformations and magnetic properties of a Cu(Ⅱ)-VO(Ⅱ) heterobinuclear complex:interaction between orthogonal magnetic orbitals[J].J.Am.Chem Soc,1982,104:2165-2176.
  • 9Journaux.Y,Kahn.O,Galy.J et al.Symmetry of the magnetic orbitals and extrange interaction in copper iron (CuⅡFeⅢ)and copper chromium (CuⅡCrⅢ) heterobinuclear complexes.crystal structure of CuFe[(fsa)2en]Cl(H2O)(CH3OH).CH3OH[J].J.Am.Chem.Soc,1983,105:7585-759
  • 10Buchler C.A.,Bass.B.C,Darling.R.et al.J.Am.Chem.Soc.1940,62,890.

引证文献4

二级引证文献4

河南大学学报（自然科学版）
2004年 第4期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部