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3-二茂铁基-2-丁烯酸/十八胺混合单分子膜的制备 被引量：1

Preparation of Mixed 3-Ferrocenyl-2-butylene acid/Octadecylamine Monolayer
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摘要 An amphiphilic ferrocene derivative 3-ferrocenyl-2-butylene acid(FCA) was synthesized. The mixed FCA/octadecylamine(ODA) monolayers on aqueous subphase were studied by means of surface pressure-molecule area(π-A) isotherm, dπ/dA-A curve and the plot of the apparent area of ODA vs x(ODA). The results indicate that the FCA itself did not form monolayer, but the mixed FCA/ODA mono- layers were stable when the mole fraction of ODA was more than 25%, the mixed monolayers possessed the best stability and the highest incompressibility when the mole ratio of FCA to ODA is 1 to 1. An amphiphilic ferrocene derivative 3-ferrocenyl-2-butylene acid(FCA) was synthesized. The mixed FCA/octadecylamine(ODA) monolayers on aqueous subphase were studied by means of surface pressure-molecule area(π-A) isotherm, dπ/dA-A curve and the plot of the apparent area of ODA vs x(ODA). The results indicate that the FCA itself did not form monolayer, but the mixed FCA/ODA mono- layers were stable when the mole fraction of ODA was more than 25%, the mixed monolayers possessed the best stability and the highest incompressibility when the mole ratio of FCA to ODA is 1 to 1.
作者 沈玉华 韩成祥 谢安建 夏兵 杨家祥
机构地区 安徽大学化学化工学院
出处 《应用化学》 CAS CSCD 北大核心 2005年第2期204-206,共3页 Chinese Journal of Applied Chemistry
基金 国家自然科学基金资助项目(20031010 20371001 20471001)
关键词 二茂铁衍生物 十八胺 混合单分子膜 制备 ferrocene derivative,octadecylamine,mixed monolayer,preparation
分类号 O626.1 [理学—有机化学]
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应用化学
2005年 第2期

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