XO_n^-的p-dπ配键与性质的关系

RELATIONSHIP BETWEEM p-dπ BONDS IN THE OXYHALIDE IONS XO - n(X=Cl,Br,I)AND THEIR PROPERTIES

引用对ＸＯ－ｎ（Ｘ＝Ｃｌ，Ｂｒ，Ｉ）进行ＣＮＤＯ计算结果定量说明Ｘ－Ｏ键中存在较强的ｐ－ｄπ配键，并讨论了与ｐ－ｄπ配键密切相关的卤素含氧酸及其盐的热稳定性、含氧酸的酸性及氧化性。

Some oxyhalide ions XO - n(X=Cl,Br,I)are discussed with reference the known date for the CNDO method. The results show that the X-O π bonds are of the p-d π coordinate covalent type. The thermal stabilities, the acidic property and the rules of oxidization depend on the p-d π bond strength.