[(n-Bu)_4N]_2[X_2Mo_4O_(10)(OCH_3)_2]的合成与表征

Synthesis and Characterization of [( n Bu) 4N] 2[X 2Mo 4O 10 (OCH 3) 2]

本文选用醌类配体菲醌和酚类配体１，２二羟基萘，合成了具有相似结构、通式为［（ｎＢｕ）４Ｎ］２［Ｘ２Ｍｏ４Ｏ１０（ＯＣＨ３）２］（Ｘ＝ＯＣ１０Ｈ６Ｏ和ＯＣ１４Ｈ８Ｏ）的二种四聚钼多酸配合物，进行了元素分析、核磁共振、红外光谱和热重分析等表征，并对菲醌与钼多酸配合时由醌式状态向酚式结构的还原进行了研究和探讨．

Prepared the complexes of [( n Bu) 4N] 2[X 2Mo 4O 10 (OCH 3) 2],where X=OC 10 H 6O and OC 14 H 8O;Characterized their structure by TG and Elemental Analysis,IR and 1 H NMR measurements;Also studied the reduction of phenanthraquinone in the coordinated reaction with polymolybdate anion.