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室温型镀Sn熔盐中Sn离子种类的研究 被引量：1

Studies of ionic species of Tin in ambient-temperature molten salt
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摘要 The ionic species in SnCl\-2-1-butylpytidinium chloride (BPC) ambient temperature molten salt electrolytes were investigated by using the computer simulation method. It was found that the Sn electrode potential was changed suddenly at 50.0% mole fraction SnCl\-2. The major ionic specie in the 33.3%SnCl\-2 melt is SnCl\+-\-3 and that in the 66.6% SnCl\-2 melt is Sn\-2Cl\+-\-5. Both SnCl\+-\-3 and Sn\-2Cl\+-\-5 existed in the 50.0%SnCl\-2 melt. The ionic species in SnCl\-2-1-butylpytidinium chloride (BPC) ambient temperature molten salt electrolytes were investigated by using the computer simulation method. It was found that the Sn electrode potential was changed suddenly at 50.0% mole fraction SnCl\-2. The major ionic specie in the 33.3%SnCl\-2 melt is SnCl\+-\-3 and that in the 66.6% SnCl\-2 melt is Sn\-2Cl\+-\-5. Both SnCl\+-\-3 and Sn\-2Cl\+-\-5 existed in the 50.0%SnCl\-2 melt.
作者 凌国平 何军辉 胡鹰
机构地区 浙江大学材料科学与工程学系 浙江大学物理系
出处 《浙江大学学报（工学版）》 EI CAS CSCD 北大核心 2001年第5期580-582,共3页 Journal of Zhejiang University：Engineering Science
基金 教育部留学回国人员科研启动基金资助项目 (U19731)
关键词 熔盐 SnCl2 电镀 镀金 氯化 水溶液 室温 金属 析出 非水电解液 ambient temperature molten salt electrodeposition of Tin ionic species of Tin
分类号 N33 [自然科学总论] TQ153 [化学工程—电化学工业]
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参考文献5

  • 1TAKAHASHI S,KOURA N.Thin metal coating from non-aqueous electrolytes[J].J Iron & Steel Jpn,1991,77(8):921-925.
  • 2TAKAHASHI S,AKIMOTO K.Development of Al plating from 1-Butylpyridinium Chloride-AlCl3 Molten Salt Electrolyte at Room-Temperature Molten Salt Baths[J].Nissin Gihou,1989,60(1):36-45.
  • 3KIRKERUD T,KLAEBOE P,OYE H A.Raman studies of SnCl2-AlKAlCl4 melts[J].J Inorg Nucl Chem,1979,41(1):189-191.
  • 4BIRD S R A,DONALDSON J D.Vibrational spectra of tin(Ⅱ) halide complexes[J].J Inorg Nucl Chem,1974,36(6):934-935.
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同被引文献13

  • 1杨家振,金一,潘伟.在室温离子液体BPBF_4中FeCl_3电化学性质的研究[J].化学学报,2004,62(20):2035-2039. 被引量：19
  • 2刘卉,陶国宏,邵元华,寇元.功能化的离子液体在电化学中的应用[J].化学通报,2004,67(11):795-801. 被引量：27
  • 3杨家振,金一,潘伟,臧树良.计时电流法测定Fe^(3+)在离子液体BPBF_4中的扩散系数[J].高等学校化学学报,2005,26(6):1146-1148. 被引量：7
  • 4M-H. Yang,I-W. Sun.Electrodeposition of antimony in a water-stable 1-ethyl-3-methylimidazolium chloride tetrafluoroborate room temperature ionic liquid[J]. Journal of Applied Electrochemistry . 2003 (11)
  • 5Katayama Y,Dan S,Miura T,et al.Electrochemical behavior of silverin 1-ethyl-3-methyl-imidazolium tetrafluoroborate molten salt. Journal of the Electrochemical Society . 2001
  • 6Bard A J,Faulkner L R.Electrochemical methods:Fundamentals andapplications. . 1980
  • 7Takahashi S,Koura N,Kohara S,et al.Technological and scientific is-sue of room-temperature molten salts. Plasmas&Ions . 1999
  • 8Patel P,Roy S,Seok K I L,et al.Synthesis and characterization of tinand antimony based composites. Materials Science and EngineeringB . 2004
  • 9Xu X H,Hussey C L.The electrochemistry of tin in the aluminum chlo-ride-1-methyl-3-ethylimidazolium chloride molten salt. Journal of the Electrochemical Society . 1993
  • 10Habboush D A,Osteryoung R A.Electrochemical studies of antimony(Ⅲ)and antimony(Ⅴ)in molten mixtures of aluminum chloride andbutylpyridinium chloride. Inorganic Chemistry . 1984

引证文献1

浙江大学学报（工学版）
2001年 第5期

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