摘要
超分子聚合物和树枝聚合物两个新概念组合形成的超分子树枝聚合物由含非共价键合成子结构的芯、支化单元、表面和空穴组成,树枝状金属-超分子聚合物(有机金属树枝聚合物或金属树枝体)是其中的一个重要分支。金属树枝体含有金属-配体相互作用和三维超支化结构,具有独特的光、电、催化功能和树枝效应,在光俘获天线、分子开关、太阳能电池、非线性光学材料、催化剂等领域有着广泛的应用。
Novel dendritic supramolecular polymers are the combination of dendritic polymers and supramolecular polymers.Dendritic metallo-supramolecular polymers,which may also be called as organometallic dendrimers or metallodendrimers,are composed of metal-ligand interactions in the core,branches,and surfaces and are of unique photoactive,electroactive,and catalytic functions.In this paper,their dendritic effects and applications in light harvesting antenna,molecular switches,polymer solar cells,nonlinear optical materials and catalysts are re- viewed.
出处
《材料导报》
EI
CAS
CSCD
北大核心
2005年第1期9-12,16,共5页
Materials Reports
