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TAMP、TAMS和TAMM晶体研究 被引量:1

Crystal Growth of TAM Compounds
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摘要 用溶液法合成出 FAMP、TAMS 和 TAMM 三种新化合物。测绘了它们在水中的溶解度曲线,采用水溶液降温法在50~31℃范围内,从 pH 值分别为6、6、10的饱和溶液中生长出TAMP、TAMS 和 TAMM 单晶。用红外光谱和 X 射线单晶分析测定出它们的分子结构和晶体结构。 Single crystals of three novel compounds of(CH_2OH)_3CNH_2(TAM)—TAM Phosphate(TAMP),TAM sulfate(TAMS)and TAMmolybdate(TAMM)—have been synthesized by aqueous solution cooling me-thod.The solubility curves for these compounds in water were plotted,andthe molecular and crystalline structures of these single crystals weredetermined by infrared absorption and X-ray diffraction analysis.
出处 《人工晶体学报》 EI CAS CSCD 1989年第3期173-178,共6页 Journal of Synthetic Crystals
关键词 有机晶体 溶液法生长 晶体结构 organic crystal solution growth crystal structure
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参考文献2

  • 1吴景贤,结构化学,1988年,7卷,2期,148页
  • 2苏根博,光学学报,1986年,6卷,9期,848页

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  • 3Li Zhengdong,Su Genbo and Wu Baichang.Growth and characterization of methyl p-hydroxybenzoate (p-MHB). Journal of Crystal Growth . 1992
  • 4LINDFORS L,FORSSEN S,WESTERGEN J,et al.Nucleation and crystal growth in supersaturated solutions of amodel drug. Journal of Colloid and Interface Science . 2008
  • 5A.K.Karnal,A.Saxena,S.Ganesamoorthy, etal.Nucleation-trap crystallizer for growth of crystals from solutions. Journal of Crystal Growth . 2006
  • 6M.Loffelmann,,A.Mersmann.How to measure supersaturation. Chemical Engineering Science . 2002
  • 7Sharma S K,Verma S,Shrivastava B B, et al.In situ measurement of pH and supersaturation-dependent growth kinetics of the prismatic and pyramidal facets of KDP crystals. Journal of Crystal Growth . 2002
  • 8V.I. Bredikhin,,G.L. Galushkina, et al.Rapid growth of DKDP crystals from high acidity solutions. Journal of Crystal Growth . 1999
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  • 10J. M. Arber,P. Norman,D. S. Urch and D. Bloor.Crystals for soft X-ray spectroscopy. Journal of Crystal Growth . 1987

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