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胺(氨)基官能化有机锂引发剂进展 被引量:1

Advance of amine containing functionalized organolithium initiators
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摘要 介绍了各种含有氮官能团的有机锂化合物的合成、特点、发展趋势以及作为负离子引发剂在合成橡胶工业中的应用 ,指出它们在减小橡胶滞后损耗、降低其滚动阻力、提高回弹性以及降低生热等方面具有十分重要的应用价值 ,其研究重点是开发具有高活性。 The synthesis, characteristics, development and application in synthetic rubber industry of amine containing functionalized organolithium initiators were introduced with 22 references. It was pointed out that elastomers produced by these initiators could exhibit improved characteristics such as reduced hysteresis loss characteristics, and the research direction of these initiators was to develop homogeneous initiators with high activity, good solubility in hydrocarbons and simple synthetic procedure.
出处 《弹性体》 CAS 2004年第6期69-73,共5页 China Elastomerics
关键词 引发剂 官能化 低生热 回弹性 引发体系 高活性 合成工艺 合成橡胶工业 锂化合物 有机 functionalized initiator anionic polymerization synthetic rubber hysteresis loss review
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参考文献22

  • 1杜正银,李锦山.官能化有机锂引发剂技术进展[J].合成橡胶工业,1999,22(4):194-198. 被引量:5
  • 2张兴英,赵素合,金关泰.应用高分子分子设计合成节能了苯橡胶I共聚物的分子设计、合成及性能[J].弹性体,1994,4(4):15-19. 被引量:4
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  • 6Lawson D F, Antkowiak T A, et al. Low-hysteresis elastomer compositions using amino-substituted aryllithium polymerization initiators[P]. US:5519086,1996.
  • 7Engel J F, Kamienski C W, et al. Functionalized amine initiators for anionic polymerization[P]. US:5523364,1996.
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  • 9Hall J E, Antkowiak T A, et al. Lithium amino magnesiate polymerization initiators and elastomers having reduced hysteresis[P]. EP:0747405 A1,1996.
  • 10Fujio R, Morita K, et al. Amine containing polymers and products therefrom[P]. EP:0709408 A1,1996.

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