摘要
苯胺、吡咯和噻吩等是重要的导电聚合物单体.光照可促进低聚物的形成,电化学技术可方便地实现单体的电聚合.目前,有关导电聚合物单体的光电聚合的报导还很少.本文研究征水溶液中、铂金属基底上,苯胺、吡咯和噻吩等单体的光电聚合过程.
The photoelectrochemical polymerization process:monomer first polymerizes intolow polymer and then the low polymer may be oxidized into polymerfilm.monomer→low polymer→polymerfilmIrradiation can accelerate the formation of low polymer.The rate of the firststep for pyrrole and thiophene is slow,and the second step for aniline is slow.When the film is formed,it can speed up the rate of film formation.
出处
《物理化学学报》
SCIE
CAS
CSCD
北大核心
1993年第2期277-280,共4页
Acta Physico-Chimica Sinica
基金
国家自然科学基金
关键词
光电聚合
导电聚合物
聚苯胺
Photoelectrochemical polymerization
Conducting polymer
Polyaniline
Polypurrole
Polythiophene
