摘要
Two SnO2+RuO2 /Ti anodes with high SnO2-concentrations were prepared by painting, sintering and annealing through a sol-gel technique. The microstructure, morphology and grain size of coatings and the electrochemical properties of the anodes were investigated by XRD, DTA, SEM, TEM and CV. It is demonstrated that the anodic coatings consist of solid solution （Sn, X）O2 （X represents Ru or Ti） phases. The average grain size of the coatings is about less than 30 nm. When the annealing temperature increases from 450 ℃ to 600 ℃, the solid solutions decompose. The crystal of the coating is equiaxial. The morphology of TiO2+SnO2/Ti coatings is a mixture of mud-flat cracking with a kind of agglomerated structure.
Two SnO_2+RuO_2 /Ti anodes with high SnO_2-concentrations were prepared by painting, sintering and annealing through a sol-gel technique. The microstructure, morphology and grain size of coatings and the electrochemical properties of the anodes were investigated by XRD, DTA, SEM, TEM and CV. It is demonstrated that the anodic coatings consist of solid solution (Sn, X)O_2 (X represents Ru or Ti) phases. The average grain size of the coatings is about less than 30 nm. When the annealing temperature increases from 450 ℃ to 600 ℃, the solid solutions decompose. The crystal of the coating is equiaxial. The morphology of TiO_2+SnO_2/Ti coatings is a mixture of mud-flat cracking with a kind of agglomerated structure.
出处
《中国有色金属学会会刊：英文版》
CSCD
2004年第6期1111-1116,共6页
Transactions of Nonferrous Metals Society of China
基金
Project ( 5 9682 0 0 6)supportedbytheNationalNaturalScienceFoundationofChina
