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Pt/YSZ电极结构形貌对传感器特性的影响 被引量:6

Effect of Electrode Appearance of the Pt/YSZ Structure on the Characteristic of Sensor
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摘要 借助交流阻抗测试技术、汽车用A F(空气与燃料的质量比 )氧传感器响应时间测量装置及SEM ,对敏感材料为Y2 O3 稳定ZrO2 多晶固体氧离子导体 (YSZ)的Pt YSZ电极结构氧传感器其特性在不同烧结温度下电极形貌的关系进行了研究 ,同时提出了一种有关Pt YSZ电极界面的形貌模型 ,采用此模型对不同烧结温度下的电极形貌Pt 空气 YSZ三相界面长度进行了定量计算。 By means of complex AC impedance and the response t im e -measuring instrument of the air-fuel ration oxygen sensor, as well as SEM, ob servation on the electrode appearance of the Pt/YSZ(yttria stabilized zirconi a) electrode structure at different firing temperature show notable effect on the Characteristic of Sensors. In addition, a new model of the electrode and ele ctrolyte interface (Pt /YSZ) was presented and the length of triple phase bound ary of electrode at different firing temperature were calculated by this model
出处 《电子测量与仪器学报》 CSCD 2004年第4期10-14,20,共6页 Journal of Electronic Measurement and Instrumentation
基金 国家科技部国家级火炬计划项目 (项目编号 :2 0 0 1EB0 0 1 1 3 1 )。
关键词 形貌 多晶 烧结温度 YSZ ZRO2 Y2O3 特性 氧离子导体 电极结构 交流阻抗 Yttria stabilized zirconia, charge migratory resista nce,complex AC impedance,Pt/Gas/YSZ triple phase boundary.
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参考文献10

  • 1[1]Junichiro MIZUSAKI, Koji AMANO, Shigeru YAMAUCHI et al. Electrode reaction at Pt,O2 (g)/stabilized zirconia interfaces. Solid State Ionics 22(1987) :313 - 322.
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  • 5江义,李文钊,阎景旺,王世忠.Pt/YSZ固体电解质界面氧的电荷传递过程研究[J].电化学,1996,2(2):157-163. 被引量:8
  • 6[7]Shigeru YAMAUCHI, Junichiro MIZUSAKI, Koji AMANO and Kazuo FUEKI. Reaction Mechanism of Zirconia Oxygen Sensors. Proceedings of the sensor symposium, 1984; 167- 172.
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  • 9孙成文,李奇,陈深,杨芝洲.Pt/YSZ氧传感器的电极电阻和响应特性[J].无机材料学报,1998,13(4):561-567. 被引量:3
  • 10[11]Verkerk M J, Hammink M W J, Burggraff A . J. Oxygen Transfer on Substituted ZrO2, Bi2O3 and CeO2 Electrolyte with platinum Electrodes. J.Electrochem.Soc., 1983;130:70- 77.

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