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SiCN薄膜在Si衬底上的沉积 被引量:1

Deposition of Silicon Carbon Nitride Film on Si (100) Substrates
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摘要 本文采用微波等离子体化学气相沉积 (MPCVD)系统 ,在单晶Si衬底上制备出了SiCN薄膜。所采用的源气体为高纯CH4和N2 ,而Si源来自于Si衬底、SiH4和Si棒。用场发射扫描电镜 (SEM)、X射线光电子能谱 (XPS)和X射线衍射谱 (XRD)对样品进行了表征与分析。结果表明 ,外加Si源、高的衬底温度、高流量N2 有助于提高样品的成膜质量。 Silicon carbon nitride (SiCN) film was synthesized on Si wafer by microwave plasma chemical vapor deposition (MPCVD) with CH4, N2 and different Si sources. The samples were characterized by field emission scanning electron microscopy (SEM), X-ray photo-emission spectroscopy (XPS) and X-ray diffraction spectroscopy. It is shown that additional Si source, high substrate temperature and high flow rate of N2 contribute to obtain a SiCN film with high quality. The film exhibits a new hexagonal SiCN phase and multibonding structure.
机构地区 清华大学化学系
出处 《人工晶体学报》 EI CAS CSCD 北大核心 2004年第6期913-917,共5页 Journal of Synthetic Crystals
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参考文献11

  • 1Morkoc H, Strite S, Gao G B, Lin M E, Sverdlov B, Bums M. Large-band-gap SiC, Ⅲ-Ⅴ Nitride and Ⅱ-Ⅵ ZnSe-based Semiconductor-device Technologies [J]. J. Appl. Phys., 1994, 76: 1363.
  • 2IvanovP A, Chelnokov V E. Recent Developments in SiC Single-crystal Electronics [J]. Semicond. Sci. Technol., 1992, 7: 863.
  • 3Liu A Y, Cohen M L. Prediction of New Low Compressibility Solids [J]. Science, 1989, 245: 841.
  • 4LiuA Y, CohenML. Structural Properties and Electronic Structure of Low-compressibility Materials:β-Si3N4 and Hypothetical α-C3N4[J] Phys. Rev.B,1990, 41: 10727.
  • 5Bendeddouche A, Berjioan R, Beche E, Schamm S, Serin V, Carles R, Hillel R. SiCN Amorphous Materials Chemical Vapor Deposited Using the Si (CH3)4-NH3-H2 System [J]. J. de Physique Ⅳ, 1995, C-5: 793.
  • 6Gomez F J, Prieto P, Elizalde E, Piqueras J. SiCN Alloys Deposited by Electron Cyclotron Resonance Plasma Chemical Vapor Deposition [J]. Appl.Phys. Lett., 1996, 69: 773.
  • 7Chen L C, Chen C K, Wei S L, Bhusari D M, Chen K H, Chen Y F, Jong Y C, Huang Y S. Crystalline Silicon Carbon Nitride: A Wide Band Gap Semiconductor [J]. Appl. Phys. Lett., 1998, 72: 2463.
  • 8Barbadillo L, Gomez F J, Hernandez M J, Piqueras J. Nitrogen Incorporation in Amorphougs SiCN Layers Prepared from Electron Cyclotron Resonance Plasmas [J].Appl.Phys. A, 1999, 68: (1999) 603.
  • 9Nakaaki I, Saito N. Optical, Electrical and Structural Properties of Amorphous SiCN:H films Prepared by RF Glow-discharge Decomposition [J]. Appl.Surf. Sci., 2001, 169-170: 468.
  • 10肖兴成,江伟辉,彭晓峰,宋力昕,胡行方.反应溅射Si-C-N薄膜的结构分析[J].功能材料与器件学报,2000,6(1):59-63. 被引量:9

二级参考文献15

  • 1Alix G, Khaled H, Francois S, et al. CVD Diamond Films: from Growth to Applications [J]. Current Appl Phys,2001.1:479.
  • 2Field J E. The Properties of Diamond[M]. Academic Press, London, 1979:332.
  • 3Edgar J H.Prospects for Device Implementation of Wide Band Gap Semiconductor[J] .J Mater Res, 1992,7:237.
  • 4Constant L, Speisser C, Le Normand F. HFCVD Diamond Growth on Cu( 111 ) :Evidence for Carbon Phase Transformations by in Situ AES and XPS[J]. Surf Sci, 1997,397:28.
  • 5Lux B, Haubner R. Diamond and Diamond-like Films and Coatings[M]. Plenum Press, New York. 1991:156.
  • 6Hartsell M L, Plano L S. Growth of Diamond Films on Copper[J]. J Mater. Res, 1992,9:3795.
  • 7Narayan J, Chen X. Laser Pattering of Diamond Films[ J]. J Appl Phys, 1992, 71: 3795.
  • 8Jiang N, Wang C L, Won J H, Joen M H, et al. Interface Characterization of Chemical Vapour Deposited Diamond on Cu and Pt Substrates Studied by Transmission Electron Microscopy[J]. Appl Surf Sci, 1997, 117/118:587-591.
  • 9Lu T Z H,Thin Solid Films,1998年,332卷,230页
  • 10WEI A X,Thin Solid Films,1998年,323卷,217页

共引文献13

同被引文献13

  • 1程文娟,张阳,江锦春,朱鹤孙.微波等离子体化学气相沉积制备SiCN结晶膜及SiCN微米棒阵列(英文)[J].人工晶体学报,2004,33(4):496-499. 被引量:2
  • 2Liu A Y, Cohen M L. Prediction of new low compressibility solids[J]. Science, 1989, 245: 841-842.
  • 3Chen L C, Yang C Y, Bhusari D M, et al. Formation of crystalline silicon carbon nitride films by microwave plasma-enhanced chemical vapor deposition[J]. Diamond and Related Materials, 1996, 5(3/5): 514-518.
  • 4Chena C W, Huang C C, Lin Y Y, et al. Optical properties and photoconductivity of amorphous silicon carbon nitride thin film and its application for UV detection[J]. Diamond and Related Materials, 2005, 14(3/7): 1010-1013.
  • 5Jedrzejowski P, Klemberg-Sapieha J E, Martinu L. Quaternary hard nanocomposite TiCxNy/SiCN coatings prepared by plasma enhanced chemical vapor deposition[J]. Thin Solid Films, 2004, 466(1/2): 189-196.
  • 6Nakayamada T, Matsuo K, Hayashi Y, et al. Evaluation of corrosion resistance of SiCN films deposited by HWCVD using organic liquid materials[J]. Thin Solid Films, 2008, 516(5): 656-658.
  • 7高鹏,徐军,朴勇,等.基体负偏压对SiCN薄膜结构和性能的影响[C]//北京国际材料周暨中国材料研讨会.北京,2006:362-368.
  • 8Sundaram K B, Alizadeh Z, Todi R M, et al. Investigations on hardness of RF sputter deposited SiCN thin films[J]. Materials Science and Engineering, 2004, 368(1/2): 103-108.
  • 9Chen C W, Huang C C, Lin Y Y, et al. The affinity of Si-N and Si-C bonding in amorphous silicon carbon nitride (α-SiCN) thin film[J]. Diamond and Related Materials, 2005, 14(8): 1126-1130.
  • 10肖兴成,江伟辉,彭晓峰,宋力昕,胡行方.反应溅射Si-C-N薄膜的结构分析[J].功能材料与器件学报,2000,6(1):59-63. 被引量:9

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