Cu(I)配合物的制备与性质表征

Preparation and properties expression of cupreous camplex

Cu(I)的配合物有广泛的用途而受到人们的普遍关注.利用CuCl2和过量的铜屑在浓盐酸介质中加热即全部生成H[CuCl2],将其直接倾入蒸馏水中便可得到大量CuCl沉淀,由此制备Cu(I)配合物方法简单.CuCl为具有闪锌矿型结构的分子晶体,遇配体溶解生成稳定的Cu(I)配合物CuLn,它们与Cu(I)离子的性质不同,能在水溶液中稳定存在,这就提供了供应水溶液中+1氧化态铜化合物的一种方法,使Cu(I)配合物的用途大为扩展.

For its extensive use. Cu (I) complex has veceived widespread concern. Heating the Copper scraps of the surfeit in thick hydrochloric acid makesH\. We can get large quantity of CuC l by pouring H\ into the distilled water. This way is relatively simple.The CuCl is a kind of structural numerator in the type of ZnS crystal and born into stable CuLn, the matchting of Cu (I).They're different from the nature of Cu (I) ion kind.They are steadily existent, which provides the method as mentioned above, making use of Cu (I)'s match loiden.