A Novel Synthesis of 3-O-Allyl-4,5,6-tri-O-benzyl-1-O-(p-methoxybenzyl)-D-myo-inositol
A Novel Synthesis of 3-O-Allyl-4, 5, 6-tri-O-benzyl-1-O- (p-methoxybenzyl)-D-myo-inositol
摘要
Highly efficient synthesis of the entitled compound was achieved from a readily availablemyo-inositol derivative. The key step involved a desymmetrization with (+)-camphor dimethylketal to give two diastereomers. The two diastereomers could be used to synthesize the samecompound by changing the orders to introduce the protective groups.
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