基元反应的活化能与反应热效应的关系

THE RELATIONSHIP BETWEEN ACTIVATION ENERGY OF ELEMENTARY HEACTION AND HEAT EFFECT OF REACTION

关于基元反应的活化能与反应热效应的关系,有些著名文献认为E_1-E_(-1)=△_rU_m,而另一些著名文献却认为E_1-E_(-1)=△_rHm,本文从几个方面论证E_1-(-1)_E=△_rUm。

Atout the vetationship between activation energy of elementary veaction and neat effect of veaction, some well known literatune think E1-E-1 =but some other well-know literatune think E1-E-1=Um. In this paper, we expound and prove E1-E-1=rUm. in several veepect.