碳酸二甲酯的合成化学

SYNTHESIS CHEMISTRY OF DIMETHYL CARBONATE

碳酸二甲酯是重要的有机化工原料之一 ,有着有机合成的新基石和绿色化工产品之美称 ,是新的燃油添加剂 ,在 2 1世纪将具有广阔的应用前景 .论述了碳酸二甲酯的合成化学 ,特别是目前工业化非光气甲醇氧化羰基化制备碳酸二甲酯的化学过程 。

Dimethyl carbonate (DMC), called as cornerstone of organic synthesis and green chemical, is one of the most important chemicals in chemical industry. It has being expected as new fuel additive in the new century. The synthesis chemistry of dimethyl carbonate was reviewed in detail, especially non phosgene oxidative carbonylation of methanol to DMC in commercial processes. And new routes of DMC synthesis are enclosed.\;