气相基元反应的活化能与反应焓变的关系

The Relation Between Activation Eenergy of Gas Elementeny Reaeticon and Enthalpy Changes

应用基元反应的过渡态理论及微观可逆性原理推导了气相基元反应正逆过程的活化能之差与热力学量之间的关系.

Based on the transition state theory and the principle of micro-reversibility, the relation between activation energy and thermodynamic quantities of gas elemntary reaction is dis-cussed.