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PHOTOBROMINATION OF SIDE-CHAIN METHYL GROUP ON METHYLNAPHTHALENES

PHOTOBROMINATION OF SIDE-CHAIN METHYL GROUP ON METHYLNAPHTHALENES
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摘要 The photobrominations of 1-methylnaphthalene (1-MN) and 2-methylnaphthalene (2-MN) were investigated by using N-bromosuccinimide (NBS) as brominating agent. The results show that under nitrogen atmosphere, side-chain methyl group on 1-MN and 2-MN can be brominated selectlvely with visible light and NBS in benzene at room temperature, and that 1-MN is photobrominated easier than 2-MN. The photobrominations of 1-methylnaphthalene (1-MN) and 2-methylnaphthalene (2-MN) were investigated by using N-bromosuccinimide (NBS) as brominating agent. The results show that under nitrogen atmosphere, side-chain methyl group on 1-MN and 2-MN can be brominated selectlvely with visible light and NBS in benzene at room temperature, and that 1-MN is photobrominated easier than 2-MN.
出处 《Journal of China University of Mining and Technology》 1995年第1期44-48,共5页 中国矿业大学学报(英文版)
关键词 methylnaphthalenes N-BROMOSUCCINIMIDE photobromination 甲基 溴化作用 ArCH2 支链
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