2－烷氧甲酰基双环［2，2，1］－5（6）－庚基丙烯酸酯的合成与共聚研究

Study on Syntheses and Copolymerization of 2-Alkoxyl Carbonyl Bicyclo[2,2,1]Hept-5(6)-yl Acrylates

探索了２－烷氧甲酰基双环［２，２，１］－５（６）－庚基丙烯酸酯的合成条件和它与甲基丙烯酸甲酯（ＭＭＡ）及丙烯腈（ＡＮ）共聚反应的竞聚率，测得它们的ｒ＿１和ｒ＿２分别为２．３１与２．４４和０．８３与０．０２。

The synthetic conditions of 2-alkoxy carbonyl bicyclo[2,2,1]-hept-5-(6)-yl acrylate were studied,the reactivity ratios of 2-AMCHAE-l with methyl methacrylate(MMA)and acrylamitrile(AN)copolvmerizations were deter-mined.when is 2-AMCHAE-1,M_2 MMA or AN respectively,the reactivi-ty ratios of the copolymerizations are:2-AMCHAE-1-Co-MMA:r_1=2.31,r_2=2.44;2-AMCHAE-1-Co-AN:r_1=0.83,r_2=0.02.