摘要
合成了一种新的钴（Ⅱ）大环配合的Ｃｏ（［１４］４，１１－ｄｉｅｎｅ－Ｎ４）Ｉ２，该配合物由元素分析、Ｘ－射线粉末衍射，红外光谱等手段表征，并进行了吸氧量测定，结果表明，该配合物具有特殊的吸氧性能，且在不同溶剂中，吸氧量按ＴＨＦ、ＰＹ、ＤＭＦ、ＤＭＳＯ顺序依次增大，在同一溶剂中，吸氧量随温度的升高而减小．
A new Co(Ⅱ) macrocyclic coordination compound is synthesized and characterized by means of elemental analyses X-ray powder diffraction and IR spectra, and its O2 uptake capacity is measured, the result has shown that the coordination compound has particular O2 uptake properties, and the O2 uptake capacity increases according to THF、PY、DMF、DMSO in turn in not alike solvent, the O2 uptake capacity decreases as tempreture increasing in alike solvent.
关键词
钴
大环配合物
合成
吸氧性能
Cobalt
Macrocylic complex
Synthese
O2 Uptake properties
