卟啉化合物的合成及其对细胞色素P－450的模拟──XⅢ．PVC和CPVC固载TPPMn（Ⅲ）OH的合成及其对惰性氢键的温和催化活化

SYNTHESIS OF PORPHYBIN COMPOUNDS AND THEIR IMITATION OF CYTOCHROME P-450 MONO-OXYGENASE──XIII.STUDY ON SYNTHESIS OF PVC AND CPVC SUPPORTED TPPMn(Ⅲ)OH AND MODERATE CATALYTIC ACTIVATION FOR INERT C-H BOND

卟啉化合物的合成及其对细胞色素Ｐ－４５０的模拟──ＸⅢ．ＰＶＣ和ＣＰＶＣ固载ＴＰＰＭｎ（Ⅲ）ＯＨ的合成及其对惰性氢键的温和催化活化俞善信，钟为标，郭灿城（湖南师范大学化学系，长沙４１００８１）（湖南大学化学化工系，长沙４１００８２）关键词高聚物，四苯...

VC-and CPVC-bonded tetraphenylmanganese(Ⅲ) porphyrin complexes have been synthesized.It is shown that the polymer-bonded metalloporphyrins are effective catalysts for oxidation of cyclohexane to cyclohexanol and cyclohexanone under moderate condition.The supported manganese porphyrins as catalysts can be used repeatedly.