摘要
Ｎ，Ｎ－二甲基苄胺催化合成丙烯酸间苯二酚环氧酯的机理高俊刚，王洪芳，袁翠红（河北大学化学系，保定０７１００２）关键词丙烯酸间苯二酚环氧酯，Ｎ，Ｎ－二甲基苄胺，催化反应机理不饱和酸环氧酯是由不饱和核酸与环氧化合物进行环氧化反应形成的一种化合物，它在涂料...
he reaction mechanism and kinetics of m-phendiol epoxy acrylatesynthesis catalyzed by dimethylbenzylamine (DMBA) have been studied. In the reaction process, the complex of acrylic acid with catalystDMBA is first formed, then the reaction between epoxy group andacrylic acid is catalyzed by it. The order of the reaction is 1, 0 and 0. 72with respect to epoxy qroup, acrylic acid and DMBA, respectively.
关键词
丙烯酸
间苯二酚
合成
环酯氧
m-phendiol epoxy acrylate, N,N-dimethyl benzylamine,catalytic reaction mechanism
