摘要
NaX沸石的改性及与乙醇缩合反应性的关联徐斌,杨春,孟中岳(南京师范大学化学系,南京210024)关键词乙醇缩合,碱性催化,NaX沸石,改性沸石分子筛的碱性质和碱催化反应的研究是近年来沸石催化中一个引人注目的课题[1-7].碱性沸石催化乙醇缩合是制备...
2CO3 MgO+KOH or MgO+NaOH was used to modify NaX zeolite for ethanol condensation reaction. The new catalyst possessed moderate base strength showed much better performance for ethanol conversion to 1-butanol. Over (NaOH)0.4-10% MgO/NaX, the conversion ofethanol was 26. 4% and the selectivity for 1-butanol was 56.4% at T=400℃, W/F=5. 6 g. h. mol-1.
关键词
钠沸石
改性
乙醇
缩合反应
thanol condensation, base catalysis, NaX zeolite,modification