电解质溶液热力学性质模型

THERMODYNAMIC MODELS FOR ELECTROLYTE SOLUTIONS

本文描述了建立电解质溶液热力学模型的理论基础,对现有的主要模型进行了分类(经验模型和理论模型),并加以评价。对目前应用甚广的 Bromley模型、Meissner模型、Pitzer和Chen模型以及本文作者近期开发的新模型进行了计算比较。提出了今后的发展方向。

The thermodynamic principle for electrolyte solutions is describedin this paper. Two kinds of models available-emperical models and theoreticalmodels are reviewed. A new model developed by the authors was compared with Bromley model, Meissner model, Pitzer model and Chen model, which are widely used in industry. The trend of study in this field is also discussed.