摘要
本文研究运用改良单纯形基本原理建立了单纯形推移计算公式,结合分光光度法首次研究并报道了V(V)-NH_2OH-PAR三元配合物的组成比,三种不同初始单纯形下,均获得组成比为2+1+2。该法简便、快速、准确度较高,且可克服传统的三元相图法需绘图等缺点。
The simplex optimization method has been used to establish the calculation formulas of simplex form passage. The composition of V(V)-NH_2OH-PAR complex system was first studied and reported, Under three different original simplex forms, we obtained the same result of 2+2+1. The proposed method was simplicity, rapid, high accuracy and eliminated the graph-drawing.
出处
《分析测试学报》
CAS
CSCD
1994年第2期66-69,共4页
Journal of Instrumental Analysis
关键词
单纯形优化法
NH2OH
PAR
络合物
钒
Simplex optimization, Spectrophotometric method,V(V)-NH_2OH-PAR.