膦桥过渡金属杂双核络合物场解吸质谱研究

Field Desorption Mass Spectrometry of Heterobinuclear Complex

本文报道了采用场解吸电离质谱(FDMS)技术获得的膦桥过渡金属杂双核络合物系列化合物的质谱图,讨论了该系列络合物的裂解规律和离子源条件下的稳定性。结果表明,FDMS技术对研究膦桥过渡金属杂双核络合物是有效的方法。

In this paper, we studied a series of new binuclear complexes of Fe-M (M=Mo, Rh, Cu, Hg) using field desorption mass spectrometry technique with satisfactory results. All the samples gave satisfactory spectra. The fragment pattern of the samples is discussed.