单纯形最优化法测定三元配合物组成比的研究

Simplex Optimization Method for the Determina-tion of Composition Ratio of Ternary Complex

本文运用单纯形最优化法，测定了Ｖ（Ⅴ）－ＰＡＲ－Ｈ＿２Ｏ＿２以及Ｗ（Ⅵ）ＰＶ－ＣＴＭＡＢ三元配合物的组成比。提出了对应于三元配合物的λｍａｘ处二元配合物也有部分吸收时的二种处理办法以及体系最初酸度调节的新看法，并经上述三元配合物体系，验证了方法的可行性，进一步完善了单纯形最优化法测配合物组成比这一手段。

The simplex optimization method has been usedto determine the compositions of complex systems V(Ⅴ)-PAR-H_2O_2 and W(Ⅵ)-PV-CTMAB.Two newmethods were introduced to treat the ternary complexsystem when corresponding binary complex absorbedpartly at the maximum absoption of ternary complex.A new viewpoint of the first acid abjustment was pro-posed.