叶绿素、染料体系光电效应的研究

THE STUDY OF PHOTOELECTRIC EFFECT IN CHLOROPHYLL AND DYES SYSTEM

叶绿素、染料体系光电效应的研究周武，杨玉国，韩允雨，周瑞龄（山东师范大学化学系，济南２５００１４）关键词叶绿素，染料，光电效应叶绿素光电性质的研究有特殊意义．７０年代开始国内外已有很多报道，它们有整流、光导、光伏和光解水制取氢和氧等性质￣［１－５］．...

Chlorophlla(Chl a )was electrodeposited on SnO_2 optical transparent electrode from isooctane-chl a solution to form chl a/SnO_2 which was used as working electrode(WE)inthe photo electrochemical cell and another SnO_2 as counter electrode. The cell contained aqueous solution of dyes and triethanolamine (TEOA).As the light source,a 150W halogenlamp was used.The curves of working voltage vs working current were meaisured underthe potential of chl a/SnO_2 electrde controlled by means of a potentiostat. Accordingto the curves,open-circuit voltage(V_(oc)),short-circuit current(I_(sc))and filling factoretc. were obtained.The change of photovoltage and photocurrent under illumination weremeasured.The output characters of photovoltage and photocurrent were obtained. Theresults indicated that Safranine T(ST)and halogenated fluorescein derivatives(FXn)hada great effect on the photoelectric parameters of the cells. The V_(oc) of the cell was about 6-8 times higher than that of the cells without ST and FXn.The increases of V_(oc) and I_(sc) were illustrated by the photoelectric effects of ST and chl a dihydrated aggregates andtheir absorption spectra. The mechanism of photoelectric effects was discussed throughthe output characters of photovoltages and photocurrents.