摘要
在CdS水悬浮液中O_2光吸收的pH效应席婵娟,李庆霖,金振声(中国科学院兰州化学物理研究所,兰州730000)关键词光吸收,光腐蚀,硫化镉以CdS为基础的光催化剂在水悬浮液中光照时,有严重的光腐蚀发生,CdS的光腐蚀有两类 ̄[1,2]:直接光腐蚀,...
The pH effect of photouptake of O_2 on CdS and Pt/CdS was investigated. The resultindicates that there are two types of mechanism for O_2 photouptake aqueous dispersionsof CdS and Pt/CdS. In acidic condition,O_2 photouptake proceeds continuously and canbe described with 1st order rate equation. In basic condition,O_2 photouptake ceaises afterhalf an hour irradiation,which is illustrated by following equations:Then,the surface of CdS is covered by Cd (OH)_2 and the O_2 uptake is hindered.
出处
《感光科学与光化学》
CSCD
1994年第2期177-181,共5页
Photographic Science and Photochemistry
基金
国家自然科学基金
关键词
光吸收
光腐蚀
硫化镉
PH值
photouptake,photocorrosion,cadmium sulfide To whom correspondence should be addressed.