杂多阴离子的相转移化学（Ⅳ）──杂多阴离子与NO的配位反应

The Phase-Transfer Chemistry of Heteropolyanions(Ⅳ)──The Coordination Reaction of Heteropolyanions with NO

杂多阴离子的相转移化学（Ⅳ）──杂多阴离子与ＮＯ的配位反应王恩波，刘霞，王作屏，许林，高丽娟（东北师范大学化学系，长春，１３００２４）关键词杂多阴离子，相转移，ＮＯ配位Ｐｏｐｅ等［１］发现表面含有配位水分子的杂多阴离子可以在相转移作用下转移到非极性溶...

In this paper,the coordination reaction between the substituted heteropolyanionswith Keggin structure{[XM(11)O(39)Z]￣(n-),X=Si,P;M=Mo,W;Z=Co(2+), Ni(2+)}, and Dawson structure{[P2W(17)O(61)Co](8-)} and the small inorganic molecules nitrogen oxide in a nonpolar solvent is studied by means of the phase-transfer chemistry of heteropolyanions, electronic absorption spectra and electron spin resonance (ESR).The experimental results show that,except the heteropolyanions for [PMo(11)O(39)Co](5-),the others can form coordination compounds with nitrogen oxide.